Amphoteric Cellulose‐Based Double‐Network Hydrogel Electrolyte Toward Ultra‐Stable Zn Anode. (17th February 2023)

• Record Type: Journal Article
• Authors: Zhang, Haodong; Gan, Xiaotang; Song, Zhiping; Zhou, Jinping
• Is Part Of: Angewandte Chemie. Volume 135:Number 13(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-02-17
• Subjects: Amphoteric Cellulose -- Aqueous Rechargeable Zinc Batteries -- Double-Network -- Hydrogel Electrolyte -- Zn Anode; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202217833
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Zinc (Zn) metal anode suffers from uncontrollable Zn dendrites and parasitic side reactions at the interface, which restrict the practical application of aqueous rechargeable zinc batteries (ARZBs). Herein, an amphoteric cellulose‐based double‐network is introduced as hydrogel electrolyte to overcome these obstacles. On one hand, the amphoteric groups build anion/cation transport channels to regulate electro‐deposition behavior on Zn (002) crystal plane enabled by homogenizing Zn 2+ ions flux. On the other hand, the strong bonding between negatively charged carboxyl groups and Zn 2+ ions promote the desolvation process of [Zn(H2 O)6 ] 2+ to eliminate side reactions. Based on the above two functions, the hydrogel electrolyte enables an ultra‐stable cycling with a cumulative capacity of 7 Ah cm −2 at 20 mA cm −2 /20 mAh cm −2 for Zn||Zn cell. This work provides significant concepts for developing hydrogel electrolytes to realize stable anode for high‐performance ARZBs. Abstract : We designed a flexible amphoteric cellulose‐based double‐network hydrogel electrolyte. The amphoteric groups not only promoted the desolvation process of [Zn(H2 O)6 ] 2+ to eliminate side reactions, but also guided the Zn 2+ deposition to inhibit dendrite growth, thus resulting in a ultra‐stable Zn anode.