In situ integration of cobalt diselenide nanoparticles on CNTs realizing durable hydrogen evolution. Issue 8 (3rd February 2022) - Ye, Hongfeng
Abstract : The CoSe2 /CNT composites are integrated as electrocatalysts for the hydrogen evolution reaction, providing a new way to construct durable electrocatalysts from transition metal compounds. Abstract : Cobalt diselenide (CoSe2 ) is considered to be a promising economical and efficient electrocatalyst for the hydrogen evolution reaction (HER). Here carbon nanotubes (CNTs) were employed as a conductive skeleton to optimize the electrocatalytic performance of CoSe2 through a simple one-step hydrothermal method. Beyond the expected, the introduction of CNTs not only accelerates electron transportation and ion diffusion, but also improves the reaction kinetics for HER by forming a CoSe2 /CNT heterointerface. Consequently, the CoSe2 /CNTs composite exhibits an optimal overpotential of 153 mV with a weight ratio of 10 : 1, and sustains a long period of 48 hours with an negligible overpotential deterioration. In addition, a Faraday efficiency of 97.67% is achieved with a H2 /O2 molar ratio of 2 : 1. Therefore, these results open up further opportunities for yielding efficient and durable hydrogen evolving electrocatalysts from low-cost transition metal compounds.