Auto-programmed synthesis of metallic aerogels: Core-shell Cu@Fe@Ni aerogels for efficient oxygen evolution reaction. (March 2021)

• Record Type: Journal Article
• Authors: Jiang, Bo; Wan, Zhe; Kang, Yunqing; Guo, Yanna; Henzie, Joel; Na, Jongbeom; Li, Hexing; Wang, Shengyao; Bando, Yoshio; Sakka, Yoshio; Yamauchi, Yusuke
• Is Part Of: Nano energy. Volume 81(2021)
• Publication Date: 2021-03
• Subjects: Transition metal-based electrocatalyst -- Core-shell aerogels -- Porous structure -- Oxygen evolution reaction -- In-situ oxidation; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2020.105644
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: Porous metallic aerogels are a new class of cutting-edge materials useful in catalysis because they combine high conductivity with low density and high surface area. However, the exploration of transition metal-based aerogels with core-shell architectures remains a fundamental challenge. Here, we report a one-step auto-programmed synthesis method to generate a core-shell Cu@Fe@Ni metallic aerogel. Electroactivating (EA) the core-shell Cu@Fe@Ni causes the Fe inner shell to migrate into the Ni outer shell and forms a highly-active catalytic hydroxide on the surface of the aerogel. The resulting EA-Cu@Fe@Ni catalysts exhibited a low OER overpotential of 240 mV at 10 mA cm -2, which is much smaller than bimetallic CuNi (320 mV), CuFe (390 mV), and RuO2 (271 mV). In-situ Raman measurements confirm that the catalyst's outer layer is composed of NiOOH doped with Fe during the electrochemical activation process, resulting in the high OER performance. This work describes the first example of a trimetallic core-shell aerogel synthesized in one step and enables another strategy for designing highly active metals/metal oxide electrocatalysts via surface reconstruction. Graphical Abstract: The highly porous core-shell Cu@Fe@Ni metallic aerogels are synthesized by using an auto-programmed synthesis method. Through the electro-activating (EA) process, they can be converted into the metal/metal oxide catalyst (EA-Cu@Fe@Ni). The EA-Cu@Fe@Ni catalyst shows the high surface area and good mass transfer of the porous structure with a high performance of oxygen evolution reaction (OER). ga1 Highlights: A highly porous core-shell Cu@Fe@Ni metallic aerogels were synthesized by using a chemical reduction synthetic method. Core-shell Cu@Fe@Niaerogelscan bein-situ converted into metal/metal oxide catalysts with a low OER overpotential. The electrochemical process undergoing surface reconstruction was confirmed by in-situ electrochemical-coupled Raman. This works opens up a new avenue for designing highly active metals/metal oxide electrocatalysts via surface reconstruction.