Experimental and DFT characterization of interphase boundaries in titanium and the implications for ω-assisted α phase precipitation. (1st June 2018)

• Record Type: Journal Article
• Authors: Li, Dongdong; Wan, Weifeng; Zhu, Lvqi; Jiang, Yong; Shao, Shouqi; Yang, Gaojing; Liu, Huiqun; Yi, Danqing; Cao, Shuo; Hu, Qingmiao
• Is Part Of: Acta materialia. Volume 151(2018)
• Page Start: 406
• Page End: 415
• Publication Date: 2018-06-01
• Subjects: Titanium -- Interface structure -- Interface energy -- Electron microscopy -- First-principles; Materials -- Periodicals; Materials science -- Periodicals; Materials -- Mechanical properties -- Periodicals; Metallurgy -- Periodicals; Chemistry, Inorganic -- Periodicals; 620.112
• DOI: 10.1016/j.actamat.2018.03.056
• Languages: English
• ISSNs: 1359-6454

Abstract

Abstract: An intricate understanding of the fundamental β→α phase transformation upon the presence of metastable ω phase is vital for tailoring the multiphase microstructures of titanium and titanium alloys for various specific applications. To approach this, the structures and energetics of heterophase interfaces among α, β, and ω in titanium were thoroughly investigated, using the combination of high-resolution transmission electron microscopy and first-principles density functional theory calculations. The results strongly suggest that metastable ω does not necessarily act as the precursor of α but can reduce the energy barrier for α nucleation in β. The ω/β interfaces acts as favorable nucleation sites for α which, once forms, tends to grow favorably into the β matrix. These findings validate the ω-assisted α nucleation mechanism, and adequately rationalize many TEM observations on titanium alloys. Graphical abstract: Image 1