Strategy to optimize the overall thermoelectric properties of SnTe via compositing with its property-counter CuInTe2. (15th February 2017)

• Record Type: Journal Article
• Authors: Zhou, Y.M.; Wu, H.J.; Pei, Y.L.; Chang, C.; Xiao, Y.; Zhang, X.; Gong, S.K.; He, J.Q.; Zhao, L.-D.
• Is Part Of: Acta materialia. Volume 125(2017)
• Page Start: 542
• Page End: 549
• Publication Date: 2017-02-15
• Subjects: Thermoelectric -- SnTe -- Composite -- Nanostructure; Materials -- Periodicals; Materials science -- Periodicals; Materials -- Mechanical properties -- Periodicals; Metallurgy -- Periodicals; Chemistry, Inorganic -- Periodicals; 620.112
• DOI: 10.1016/j.actamat.2016.11.049
• Languages: English
• ISSNs: 1359-6454

Abstract

Abstract: SnTe, a lead-free analogue of PbTe, exhibits inferior thermoelectric performance due to its intrinsically high carrier concentration, and thus too low Seebeck coefficient and high thermal conductivity. To optimize the overall properties of SnTe, we composited SnTe with the other compound with opposite performance. CuInTe2 is a good choice due to its low carrier concentration, high Seebeck coefficient and relatively low thermal conductivity. As a result, the most optimized properties can be obtained in CuSnm InTem+2 when m = 7, and an enhanced figure of merit ZT can be obtained, ∼1.0 at 873 K, which is a three-fold increase for pure CuInTe2 and one-fold increase for pure SnTe. The overall properties are optimized much greater than the expectation, which was estimated through Effective Medium Theory (EMT). Such deviation can be ascribed to the existence of high density of coherent nanostructures. Graphical abstract: To optimize the overall properties of SnTe, we composited SnTe with the other compound with opposite performance, CuInTe2 is a good choice. The most optimized properties can be obtained in CuSnm InTem+2 when m = 7, and an enhanced figure of merit ZT can be obtained, ∼1.0 at 873 K, which is a three-fold increase for pure CuInTe2 and one-fold increase for pure SnTe. Image 1