Defect-mediated vortex multiplication and annihilation in ferroelectrics and the feasibility of vortex switching by stress. (15th April 2018)

• Record Type: Journal Article
• Authors: Yuan, Shuai; Chen, W.J.; Ma, L.L.; Ji, Ye; Xiong, W.M.; Liu, J.Y.; Liu, Y.L.; Wang, Biao; Zheng, Yue
• Is Part Of: Acta materialia. Volume 148(2018)
• Page Start: 330
• Page End: 343
• Publication Date: 2018-04-15
• Subjects: Ferroelectrics -- Vortex -- Mechanical switching -- Defect engineering; Materials -- Periodicals; Materials science -- Periodicals; Materials -- Mechanical properties -- Periodicals; Metallurgy -- Periodicals; Chemistry, Inorganic -- Periodicals; 620.112
• DOI: 10.1016/j.actamat.2018.01.018
• Languages: English
• ISSNs: 1359-6454

Abstract

Abstract: The possibility of switching the direction of the dipole toroidal moment in ferroelectrics provides exciting opportunities for development of novel nanoscale memory and logic devices. However, a practical control of vortex chirality is rather challenging at present stage, not to mention via mechanical methods. In this paper, we performed the phase-field simulations to show that mechanical switching of vortex chirality can be achieved in ferroelectric nanoplatelet via defect engineering. After introducing a void defect in the nanoplatelet, relative stability of single-vortex state and multi-vortices state is found to be altered. Importantly, during stress-induced vortex multiplication process, the void is a favored nucleation core of new vortex; meanwhile, vortices tend to annihilate away from the void during a vortex annihilation process. As the favored regions of vortex nucleation and annihilation are not the same, a deterministic mechanical switching of vortex chirality can be achieved. The effects of temperature, shape of the nanoplatelet, void size, as well as void position, on the defect-mediated vortex switching behaviors are systematically revealed. Our study demonstrates the feasibility of vortex switching by mechanical loads and provides a route to control and develop electromechanical devices based on ferroic vortices.