Insights into seasonal-variability of SVOCs, morpho-elemental and spectral characteristics of PM2.5 collected at a dense industrial site: Faridabad, Haryana, India. (May 2023)

• Record Type: Journal Article
• Authors: Shankar, Shobhna; Gadi, Ranu; Bajar, Somvir; Yadav, Neha; Mandal, Tuhin K.; Sharma, Sudhir K.
• Is Part Of: Chemosphere. Volume 323(2023)
• Publication Date: 2023-05
• Subjects: SVOCs -- n-Alkanes -- PAHs -- PAEs -- Morphology -- FTIR; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2023.138204
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: The development-oriented anthropogenic activities have led to intensive increase in emission of various organic pollutants, which contribute considerably to human health risk. In the present study, chemical, physical and spectral characterisation of fine particulate matter (PM2.5 ), collected at Faridabad city, in northern India, were examined. Seasonal variation of organic compounds [n-alkanes, polyaromatic hydrocarbons (PAHs) and phthalic acid esters (PAEs)], and potential health risk of Polyaromatic hydrocarbons (PAHs) exposure using toxic equivalency potential (TEQ) approach had been assessed. These showed seasonal average values ranging from 156.4 ± 57.0 ng/m 3 to 217.6 ± 72.9 ng/m 3, 98.0 ± 21.4 ng/m 3 to 177.8 ± 72.8 ng/m 3, and 30.9 ± 11.9 ng/m 3 to 82.5 ± 29.2 ng/m 3, respectively, with the highest value for winter. It is noteworthy that unlike, n-alkanes and PAEs, PAHs were least during spring. The high molecular weight PAHs (BaP, BkF, DahA and IcdP) were found to exhibit higher TEQ values (ranging from 0.7 to 9.7) despite of their lower concentrations. The PAH diagnostic ratio, carbon preference index and total index revealed the enhanced impact of biogenic sources of emissions in comparison to diesel emission sources during winter. Graphical abstract: Image 1 Highlights: The maximum concentration of organic-compounds were observed during winter > spring > post monsoon. The 5, 6-rings PAHs contributed the least in post-monsoon > winter > spring (27–33%), exhibited the highest TEQ values. ' Even-C' n-alkanes showed increased correlations: biogenic origin, supported for the same by IR-spectra. Heterogeneity in shapes of particles differed in elemental composition, specifying characteristic feature for source.