Sulfinic Acids in Organic Synthesis: A Review of Recent Studies. Issue 8 (9th July 2021)

• Record Type: Journal Article
• Authors: Bao, Ruwei; Feng, Yanping; Deng, Danfeng; Huang, Dayun; Sun, Xiangyu
• Is Part Of: Asian journal of organic chemistry. Volume 10:Issue 8(2021)
• Page Start: 1884
• Page End: 1896
• Publication Date: 2021-07-09
• Subjects: sulfinic acid -- radical -- nucleophile -- electrophile; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.202100331
• Languages: English
• ISSNs: 2193-5807

Abstract

Abstract: Decade advances of sulfinic acids (2010‐2021) were summarized via four categories by mechanisms: (1) sulfonyl radicals (2) RS radicals; (3) electrophilic intermediates; (4) nucleophilic S‐reagents. Their reactions with alkenes, alkynes, propiolic acids, cinnamic acids, allenes, ynones, azides, enynals, aldehydes, ketones, o ‐aryl isocyanides, arenes, quinoline N ‐oxides, disulfides, diselenides, thiophenol, P(O)‐H compounds, nitriles, alcohols, nitroso benzenes and dizo compounds will be discussed. Abstract : Decade advances of sulfinic acids (2010‐2021) were summarized via four categories by mechanisms: (1) sulfonyl radicals (2) RS radicals; (3) electrophilic intermediates; (4) nucleophilic S‐reagents.