Recent Progress in the C−N Bond Formation via High‐Valent Group 9 Cp*M(III)‐Catalyzed Directed sp2 C−H Activation. Issue 11 (16th September 2020)

• Record Type: Journal Article
• Authors: Sk, Md Raja; Bera, Sourav Sekhar; Basuli, Suchand; Metya, Abhisek; Maji, Modhu Sudan
• Is Part Of: Asian journal of organic chemistry. Volume 9:Issue 11(2020)
• Page Start: 1701
• Page End: 1717
• Publication Date: 2020-09-16
• Subjects: C−H activation -- C−N bond formation -- cobalt(III) -- rhodium(III) -- iridium(III); Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.202000367
• Languages: English
• ISSNs: 2193-5807

Abstract

Abstract: The presence of nitrogen atom in a wide variety of organic compounds called for the use of powerful C−H activation strategy in the C−N bond formation. Pentamethylcyclopentadienyl (Cp*) based, high‐valent, group 9 transition‐metal complexes have shown a great potential as catalysts in the C−H activation/functionalization over the years. This minireview summarizes recent progress made in the context of C−N bond formation via catalytic (sp 2 )C−H activation with Cp*M(III) (M=Co, Rh and Ir) catalysts. A general plausible mechanism is briefly discussed at the beginning, and then results are arranged according to metal cobalt, rhodium and iridium, respectively. Abstract : Recent advances in the C−N bond formation via (sp 2 ) C−H activation with group 9 transition‐metal catalysts, Cp*M(III) (M=Co, Rh, Ir) have been summarized in the current minireview. With the brief discussion on the general plausible mechanism, different reports are presented and categorized according to the metals.