Manipulation of mechanical and thermal properties of graphene oxide/nanoclay/unsaturated polyester hybrid nanocomposites by the surface chemistry and nanofiller composition. (March 2023)

• Record Type: Journal Article
• Authors: Farshidfar, Ali; Bazgir, Saeed; Katbab, Ali Asghar; Vaziri, Ali
• Is Part Of: Polymer testing. Volume 120(2023)
• Publication Date: 2023-03
• Subjects: Polyester -- Graphene oxide -- Nanoclay -- Mechanical properties -- Nanocomposites; Polymers -- Testing -- Periodicals; Polymères -- Tests -- Périodiques; 620.1920287
• DOI: 10.1016/j.polymertesting.2023.107951
• Languages: English
• ISSNs: 0142-9418

Abstract

Abstract: Dispersion of platelet-like nanominerals in low-viscous resins is a serious challenge; which arises from the strong interactions among the large surface area of the layers. Herein, we improved the dispersion of graphene oxide (GO) within unsaturated polyester (UP) resin and synergistically enhanced the mechanical and thermal properties of the resulting nanocomposites. In a multi-stage manner, GO was incorporated into a novel hybrid structure before adding to the polymer matrix alongside with benefited from the advantage of surface functionalization. Functional hybrid nanofiller skeletons comprising GO and nanoclay (NC) were designed and prepared at different composition ratios (25:75, 50:50 and 75:25) and different surface chemistries via modification with two thermal-resistant silane coupling agents, namely (3-Aminopropyl) triethoxysilane (APTES) and 3-(trimethoxysilyl) propyl methacrylate (MPS). The optimal loading of different hybrid structures into UP has been examined by applying three loading levels (0.25, 0.50 and 1.00 wt%). The results indicated the synergistic effects of GO and NC on the mechanical properties of UP, where the composition ratio of the hybrid constituents played a key role. Moreover, it was demonstrated that the range of composition ratio for the realization of synergistic reinforcement is strongly affected by the surface chemistry of the GO and NC. For UP matrix reinforced with APTES-modified hybrid nanofillers of GD:CD at 50:50 w/w composition, a higher tensile modulus compared to blank UP (≈+21.5%) was obtained due to boosted dispersion of nanoplatelets in UP matrix. The results of DMTA and TGA analyses suggested that there are two different UP/GO and UP/NC interfacial interactions in the composites containing unmodified hybrid nanofillers. However, after modification of hybrid nanofillers, the homogeneous dispersion of nanoplatelets boosted the interfacial interactions between nanofillers and polymer, such that higher properties were obtained. Highlights: Visualized the role of surface chemistry on dispersion of graphene oxide (GO) and nanoclay (NC) in unsaturated polyester (UP). Effect of surface functionalization on the thermomechanical behavior of GO/NC/UP nanocomposites. Functionalization of hybrid UP nanocomposites by silane coupling agents, APTES and MPS. Synergistically enhanced mechanical and thermal properties of resulting nanocomposites.