Impact of trees on gas concentrations and condensables in a 2-D street canyon using CFD coupled to chemistry modeling. (15th April 2023) - Wang, Yunyi
Abstract: Trees grown in streets impact air quality by influencing ventilation (aerodynamic effects), pollutant deposition (dry deposition on vegetation surfaces), and atmospheric chemistry (emissions of biogenic volatile organic compounds, BVOCs). To qualitatively evaluate the impact of trees on pollutant concentrations and assist decision-making for the greening of cities, 2-D simulations on a street in greater Paris were performed using a computational fluid dynamics tool coupled to a gaseous chemistry module. Globally, the presence of trees has a negative effect on the traffic-emitted pollutant concentrations, such as NO2 and organic condensables, particularly on the leeward side of a street. When not under low wind conditions, the impact of BVOC emissions on the formation of most condensables within the street was low owing to the short characteristic time of dispersion compared with the atmospheric chemistry. However, autoxidation of BVOC quickly forms some extremely-low volatile organic compounds, potentially leading to the formation of ultra-fine particles. Planting trees in streets with traffic is only effective in mitigating the concentration of some oxidants such as ozone (O3 ), which has low levels in cities regardless of this, and hydroxyl radical (OH), which may slightly lower the rate of oxidation reactions and the formation of secondary species in the street. Graphical abstract: Highlights: The presence of trees in streets may lead to a decrease in O3 and OH concentrations. Aerodynamic effect leads to a large increase of traffic-emitted pollutants. Unless wind speed is low, most condensables are not impacted by tree VOC emissions. Autoxidation is a key mechanism for fast chemistry in street canyons. Extremely-low volatile organics formed in streets may impact the number of particles.