Electron donor–acceptor complex enabled cascade reaction of unprotected o-anilide aryl chlorides for heterocycle synthesis. Issue 5 (24th January 2023)

• Record Type: Journal Article
• Authors: Yang, Zhu-Sheng; Tang, Wen-Xin; Zhang, Bei-Bei; Sun, De-Qun; Chen, Kun-Quan; Chen, Xiang-Yu
• Is Part Of: Organic chemistry frontiers. Volume 10:Issue 5(2023)
• Page Start: 1219
• Page End: 1223
• Publication Date: 2023-01-24
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/d2qo01863b
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : An electron donor–acceptor complex strategy that enabled photoactivation of aryl chlorides has been reported with the toluene anion or t BuOK as the electron donor. Abstract : An electron donor–acceptor (EDA) complex strategy that enabled photoactivation of unprotected o -anilide aryl chlorides has been reported. This EDA strategy provides a simple approach for the synthesis of several heterocycles. In this strategy, the toluene anion or t BuOK forms an EDA complex with aryl chlorides.