Observation of two-step spin transition in iron(ii) 4-amino-1, 2, 4-triazole based spin crossover nanoparticles. Issue 10 (24th February 2023)

• Record Type: Journal Article
• Authors: Lalioti, Nikolia; Giannopoulou, Efstathia; Charitos, Alexander; Parthenios, John; Malina, Ondrej; Polaskova, Michaela; Kalarakis, Alexandros; Tangoulis, Vassilis
• Is Part Of: Dalton transactions. Volume 52:Issue 10(2023)
• Page Start: 2937
• Page End: 2941
• Publication Date: 2023-02-24
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt04118a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A synthetically controllable two-step spin transition was observed in iron(ii ) spin crossover nanoparticles of the dehydrated one-dimensional coordination polymer [Fe(NH2 trz)3 ]Br2 (NH2 trz = 4-amino-1, 2, 4-triazole) using the reverse micellar method. Abstract : A synthetically controllable two-step spin transition was observed in iron(ii ) spin crossover nanoparticles of the dehydrated one-dimensional coordination polymer [Fe(NH2 trz)3 ]Br2 (NH2 trz = 4-amino-1, 2, 4-triazole) using the reverse micellar method. The change from two-step to one-step hysteretic characteristics succeeded by changing the reaction time.