Biocompatible cellulose acetate supported ammonium based ionic liquid membranes; way forward to remediate water pollution. (May 2023)

• Record Type: Journal Article
• Authors: Khalid, Amina; Zulfiqar, Sana; Tabassum, Noshabah; Khan, Amir Sada; Abid, Muhammad Amin; Akhtar, Muhammad Saeed; Al-Misned, Fahad; Aljuwayid, Ahmed Muteb; Zahmatkesh, Sasan; Asif, Saira
• Is Part Of: Chemosphere. Volume 322(2023)
• Publication Date: 2023-05
• Subjects: Ionic liquids -- Hydroxyapatite -- Adsorption -- Wastewater treatment -- Antibacterial assessment; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2023.138151
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Dyes contaminated water has caused various environmental and health impacts in developing countries especially Pakistan due to different industrial activities. This issue has been addressed in present study by fabricating biocompatible ionic liquid (IL) membranes for the remediation of Crystal violet (CV) dye from contaminated water. Novel ammonium-based IL such as Triethyl dimethyl ammonium sulfate ([C3 A][C2 H6 ]SO4 ); (A2) was synthesized and further functionalized with hydroxyapatite (HAp; extracted from refused fish scales) resulting in the formation of HA2. Furthermore, A2 and HA2 were then used to fabricate the cellulose acetate (CA) based membranes with different volume ratios. The physicochemical properties of membranes-based composite materials were investigated using FTIR, XRD, and TGA and used for the adsorption of CV in the closed batch study. In results, CA-HA2 (1:2) showed higher efficiency of 98% for CV reduction, after the contact time of 90 min. Kinetic studies showed that the adsorption of CV followed the pseudo-second-order kinetic model for all adsorbents. The antibacterial properties of the synthesized membrane were investigated against gram-positive strain, S. aureus and CA-A2 (1:1) showed better antibacterial properties against S. aureus. The developed membrane is sustainable to be used for the adsorption of CV and against bacteria. Graphical abstract: Image 1 Highlights: One pot synthesis of ammonium based ionic liquids coded as A2 and HA2. Fabrication of CA based biocompatible ionic liquid membranes (ILMs). Synthesized ILMs was proved as best adsorbents towards CV dye. Antibacterial nature of synthesized ILMs was tested against a S. aureus. PSO was acted as the best fitted kinetic model towards the adsorption of CV.