Voltage Mediated Enhances Lithium‐Ion Storage in LiTiOPO4‐y with Oxygen Vacancy. Issue 3 (17th January 2023)

• Record Type: Journal Article
• Authors: Gu, Xiujuan; Cai, Yanjun; Yao, Xiang; Tian, Hualing; Su, Zhi
• Is Part Of: ChemistrySelect. Volume 8:Issue 3(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-01-17
• Subjects: Anode -- Lithium-ion battery -- Titanates -- Hydrothermal synthesis -- Oxygen Vacancy; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.202203329
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: The oxygen vacancy modulated LiTiOPO4‐y was synthesized by simple hydrothermal and high‐temperature solid‐phase methods. X‐ray diffraction (XRD) test data analyses reveal that the density of oxygen defects in LiTiOPO4‐y can be affected by the hydrothermal reaction time. The electron paramagnetic resonance (EPR) showed signal peaks at g=2.003, which proved that oxygen defects were generated. X‐ray photoelectron spectroscopy (XPS) further demonstrated that oxygen defects exist in LiTiOPO4‐y, which led to the partial conversion of Ti 4+ to Ti 3+ . The capacity of LiTiOPO4 was limited (less than 161 mAh g −1 ) by cycling potential range (0.5–3.0 V). The oxygen‐deficient LiTiOPO4‐y was used to enhance lithium‐ion storage performance by mediating voltage from 0.01 to 3.0 V. The initial capacity of oxygen‐deficient LiTiOPO4‐y, which was synthesized after hydrothermal treatment for 18 h, with an exposed (121) face, reached 563.5 mAh g −1 at the current density of 500 mA g −1 . After 1500 cycles, the specific discharge capacity kept at 397.2 mAh g −1 . In the oxygen‐defective LiTiOPO4‐y, multiple coordination unsaturated sites are exposed, which can not only significantly enhance ion diffusion and charge transfer, but also promote Li + to more storage sites. Abstract : The oxygen vacancy modulated LiTiOPO4‐y was synthesized by simple hydrothermal and high‐temperature solid‐phase methods. The oxygen‐deficient LiTiOPO4‐y was used to enhance lithium‐ion storage performance by mediating voltage from 0.01 V to 3.0 V. Oxygen vacancies effectively promote ion diffusion and charge transfer and provide more Li + storage sites. LiTiOPO4‐y exhibits high capacity and long‐term cycle performance when used as an anode for lithium‐ion batteries.