Front Cover: Synthesis and Characterization of a Calcium‐Pyrazolonato Complex. Observation of In‐Situ Desolvation During Micro‐Electron Diffraction (Z. Anorg. Allg. Chem. 5/2023). Issue 5 (28th February 2023)

• Record Type: Journal Article
• Authors: Mies, Thomas; Schürmann, Christian; Ito, Sho; White, Andrew J. P.; Crimmin, Mark R.; Barrett, Anthony G. M.
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 649:Issue 5(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-02-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.202300027
• Languages: English
• ISSNs: 0044-2313

Abstract

Abstract : The cover picture shows the microcrystalline particle size of the Ca‐pyrazolonato complex with its diffraction pattern under micro‐ED conditions. The pattern could be identified to show a Ca‐pyrazolonato complex with an axial water ligand. The indicated shift along the b‐axis of the diffraction pattern which was attributed to the loss of a water ligand from the Ca‐pyrazolonato complex under the applied conditions of the microED measurement resulted in a second structure solution. This underlines that these conditions can result in the desolvation of highly electrophilic and oxophilic metal complexes (Ca) (DOI: 10.1002/zaac.202200294 ).