Resonant inelastic x-ray scattering from U3O8 and UN. (28th February 2023)

• Record Type: Journal Article
• Authors: Lawrence Bright, Eleanor; Xu, Lei; Harding, Lottie M; Springell, Ross; Walters, Andrew C; Sundermann, Martin; Garcia-Fernandez, Mirian; Agrestini, Stefano; Caciuffo, Roberto; van der Laan, Gerrit; Lander, Gerard H
• Is Part Of: Journal of physics. Volume 35:Number 17(2023)
• Publication Date: 2023-02-28
• Subjects: U3O8 -- UN -- resonant inelastic x-ray scattering; Condensed matter -- Periodicals; Matière condensée -- Périodiques; Vaste stoffen; Vloeistoffen; Natuurkunde; Electronic journals; Computer network resources; 530.4105
• DOI: 10.1088/1361-648X/acb8f4
• Languages: English
• ISSNs: 0953-8984

Abstract

Abstract: Resonant inelastic x-ray scattering (RIXS) using an incident energy tuned to the uranium N 4, 5 absorption edges is reported from epitaxial films of α -U3 O8 and UN. Theory shows that for U3 O8 the multiplets associated with a 5 f 1 configuration with a ground state of 2 F 5 / 2 and the excited state of 2 F 7 / 2 are observed. However, the strong transition predicted at a transfer energy of 1.67 eV is not observed. We assume this is a consequence of the intermediate state lifetime broadening due to interaction with continuum states when the transferred energy exceeds the onset of the continuum in the presence of the core hole. This hypothesis is supported by the results obtained for the 5 f -itinerant system UN, where no sharp transitions have been observed, although the broad scattering response centred at ∼1 eV is considered a signature of a predominantly 5 f 3 configuration in this band-like semi-metallic system. These experiments and theory add important information on these materials, both of which have been investigated since the 1960s, as well as whether RIXS at the uranium N edge can become a valuable tool for actinide research.