Dinuclear indium phthalocyanine doped in PMMA glass used as nonlinear optical limiter. Issue 2 (1st November 2022)

• Record Type: Journal Article
• Authors: Zhang, He; Li, Lucheng; Wang, Luyi; Chen, Jun; Wang, Jing; Liu, Yang; Zhang, Huijie; Wang, Qiang
• Is Part Of: Molecular Systems Design and Engineering. Volume 8:Issue 2(2023)
• Page Start: 240
• Page End: 250
• Publication Date: 2022-11-01
• Subjects: Chemistry -- Molecular aspects -- Periodicals; Chemical engineering -- Molecular aspects -- Periodicals; Nanotechnology -- Periodicals; 620.5
• DOI: 10.1039/d2me00177b
• Languages: English
• ISSNs: 2058-9689

Abstract

Abstract : A novel dinuclear indium phthalocyanine (In-Pc-In ) is synthesized and doped in PMMA, the resulting In-Pc-In-PMMA can greatly suppress aggregation between Pc units. As a result, the In-Pc-In-PMMA show superior nonlinear absorption behaviors than the In-Pc-In-THF samples. Abstract : The development of effective laser protectors to protect human eyes and all optical and photoelectric sensors from temporary or permanent damage caused by laser beams is both of great military significance and a focus of social and public security. In this work, a blue glass of In-Pc-In-PMMA is prepared by doping dinuclear indium phthalocyanine (In-Pc-In ) into polymethyl methacrylate (PMMA ) glass. The photophysical and nonlinear optical limiting behaviors are investigated and compared with In-Pc-In-THF solution (In-Pc-In-THF ). The results indicate that the fluorescence lifetimes of In-Pc-In-THF are τ 1 = 0.49 ns ( A 1 = 9.3%) for the monomer and τ 2 = 5.51 ns ( A 2 = 90.7%) for the dimer. However, for the In-Pc-In-PMMA sample, the fluorescence lifetimes are significantly different from those of In-Pc-In-THF, whose fluorescence lifetimes are τ 1 = 1.16 ns ( A 1 = 51.4%) for the monomer and τ 2 = 4.47 ns ( A 2 = 48.6%) for the dimer, indicating that the fluorescence lifetimes of In-Pc-In-PMMA are dominated by monomers and supplemented by dimers. As a result, the In-Pc-In-PMMA glass presents a larger nonlinear absorption coefficient than that of In-Pc-In-THF solution, which provides a new concept for developing high-performance and practical optical-limiting devices.