LiMn0.8Fe0.2PO4@C cathode prepared via a novel hydrated MnHPO4 intermediate for high performance lithium-ion batteries. Issue 4 (20th January 2023)

• Record Type: Journal Article
• Authors: Zeng, Taotao; Liu, Dai-Huo; Fan, Changling; Fan, Runzheng; Zhang, Fuquan; Liu, Jinshui; Yang, Tingzhou; Chen, Zhongwei
• Is Part Of: Inorganic chemistry frontiers. Volume 10:Issue 4(2023
• Page Start: 1164
• Page End: 1175
• Publication Date: 2023-01-20
• Subjects: Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2qi02306g
• Languages: English
• ISSNs: 2052-1553

Abstract

Abstract : A highly stable intermediate hydrated MnHPO4 is used to synthesize a well-crystallized LiMn0.8 Fe0.2 PO4 @C cathode, which exhibits a high electrical conductivity of 6.823 × 10 −2 S cm −1 and excellent cycling stability with a capacity retention of 98.62%. Abstract : With the rapid development of global electro-mobility and the impact of the Russian–Ukrainian war, the increasing cobalt and nickel prices have resulted in supply chain issues for the lithium-ion battery industry. Several types of cathode materials based on low-cost metals, such as manganese and iron, have been widely studied for lithium-ion batteries. Herein, a well-crystallized LiMn0.8 Fe0.2 PO4 @C cathode with a homogeneous structure is synthesized using hydrated MnHPO4 as the precursor. Due to the synergistic effect of oxalic acid on the chelation and reduction of transition metals, a highly stable intermediate hydrated MnHPO4 is constructed, which exhibits a similar structure to LiMnPO4, further promoting the structural transformation from MnHPO4 to LiMnPO4 . The obtained LiMn0.8 Fe0.2 PO4 @C exhibits a high electrical conductivity of 6.823 × 10 −2 S cm −1 and excellent cycling stability with a capacity retention of 98.62% after 200 cycles. This work provides a scalable route for the design of low-cost and high-performance cathode materials for commercial lithium-ion batteries.