Construction and characterization of highly stretchable ionic conductive hydrogels for flexible sensors with good anti-freezing performance. (15th March 2023)

• Record Type: Journal Article
• Authors: Zhang, Chenyan; Wang, Jikui; Li, Shuo; Zou, Xinquan; Yin, Huixian; Huang, Yicheng; Dong, Feilong; Li, Peiyuan; Song, Yaoting
• Is Part Of: European polymer journal. Volume 186(2023)
• Publication Date: 2023-03-15
• Subjects: Sensor -- Anti-freezing -- Conductive hydrogel; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2023.111827
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical abstract: Highlights: Anti-freezing conductive semi-IPN hydrogel was constructed by PAM, SA and LiCl. Sodium alginate enhanced mechanical toughness (elongation at break ∼2100%). LiCl contributed to sensitivity (GF = 17.45 in high strain) and anti-freezing property. PAM/SA/3M LiCl hydrogel could maintain stretchable and conductive at −30 °C. Abstract: As an ideal material for flexible sensors, electrically conductive hydrogels (ECHs) has been faced with water loss and easy freezing, which affects the conductive and tensile properties. Polyacrylamide/sodium alginate/LiCl (PAM/SA/LiCl) hydrogel was constructed to enhance the anti-freezing property without deficiencies of tensile and electrical performance. A semi-interpenetrating network (semi-IPN) was formed by PAM and SA through hydrogen bonding, which performed excellent mechanical property (fracture strain 2100%, fracture stress 110 KPa). LiCl contributed to the high ionic conductivity (up to 21.7 S/m) and sensitivity (Gauge Factor (GF) = 17.45). Double hydrogen bonding of SA and PAM, hydration of LiCl and ion interaction between SA and lithium ion improved the anti-freezing performance and mechanical property of the hydrogel together. The proportion of non-freezing water in system was proved to be significantly increased. The comprehensive properties of the hydrogels were evaluated and PAM/SA/3M LiCl hydrogel kept conductive without obvious loss of stretchability at −30 °C. The PAM/SA/LiCl hydrogel integrates remarkable toughness, conductivity, sensitivity and anti-freezing property, which is a suitable choice in smart wearable devices, soft robots and medical monitoring.