Innenrücktitelbild: Chirales Porphyrin durch Einbau in metallorganisches Gerüst erlaubt fotoleitende Filme für die Detektion von zirkular polarisiertem Licht (Angew. Chem. 10/2023). (10th February 2023)

• Record Type: Journal Article
• Authors: Li, Chun; Schopmans, Henrik; Langer, Lukas; Marschner, Stefan; Chandresh, Abhinav; Bürck, Jochen; Tsuchiya, Youichi; Chihaya, Adachi; Wenzel, Wolfgang; Bräse, Stefan; Kozlowska, Mariana; Heinke, Lars
• Is Part Of: Angewandte Chemie. Volume 135:Number 10(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-02-10
• Subjects: BINOL -- Chirales Porphyrin -- Fotodetektoren -- Metallorganische Gerüste -- Zirkular Polarisiertes Licht; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202300983
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract : A chiral metal‐organic framework film with optoelectronic properties based on functionalized porphyrin molecules is presented by Mariana Kozlowska, Lars Heinke et al. in their Research Article (e202217377) . While the porphyrin molecules in solution (red) are planar, as common porphyrin, the porphyrin cores are twisted and chiral upon assembly in the metal‐organic framework. The close packing and the crystalline order of the porphyrin cores in the film result in excellent photoconduction properties and sensitivity to circularly polarized light.