Oxidative carbonylation of N-protected indoles by Rh(iii)-zeolites. Issue 16 (7th February 2023)
- Record Type:
- Journal Article
- Title:
- Oxidative carbonylation of N-protected indoles by Rh(iii)-zeolites. Issue 16 (7th February 2023)
- Main Title:
- Oxidative carbonylation of N-protected indoles by Rh(iii)-zeolites
- Authors:
- Van Minnebruggen, Sam
Marquez, Carlos
Krasniqi, Besir
Janssens, Kwinten
Van Velthoven, Niels
Vercammen, Jannick
De Soete, Benoit
Bugaev, Aram
De Vos, Dirk - Abstract:
- Abstract : The oxidative carbonylation of N -protected indoles was investigated to directly synthesize indole-3-carboxylic acids. Abstract : The oxidative carbonylation of N -protected indoles was investigated to directly synthesize indole-3-carboxylic acids. Using Rh(iii )-zeolites as heterogeneous catalysts, the single-site Rh-species reach unprecedented activities (>100 turnovers), while the metal is readily recovered after reaction. X-ray absorption spectroscopy (XAS) provided evidence for site-isolation of Rh(iii ) species on the zeolite.
- Is Part Of:
- Chemical communications. Volume 59:Issue 16(2023)
- Journal:
- Chemical communications
- Issue:
- Volume 59:Issue 16(2023)
- Issue Display:
- Volume 59, Issue 16 (2023)
- Year:
- 2023
- Volume:
- 59
- Issue:
- 16
- Issue Sort Value:
- 2023-0059-0016-0000
- Page Start:
- 2319
- Page End:
- 2322
- Publication Date:
- 2023-02-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc05953c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 25961.xml