Promoted elimination of metronidazole in ferrous ions activated peroxydisulfate process by gallic acid complexation. (April 2023)

• Record Type: Journal Article
• Authors: Tang, Shoufeng; Zhu, Eryu; Zhai, Zhihui; Liu, Huilin; Wang, Zhibing; Jiao, Tifeng; Zhang, Qingrui; Yuan, Deling
• Is Part Of: Chemosphere. Volume 319(2023)
• Publication Date: 2023-04
• Subjects: Complexing agent -- Fe2+ reduction -- Sulfate radical -- Metronidazole removal; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2023.138025
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: We applied gallic acid (GA) as the complexing agent to stabilizing the regeneration of Fe 2+ during the Fe 2+ /peroxydisulfate (PDS) Fenton-like reaction for promoting the removal of metronidazole (MTZ). This research evaluated the elimination of MTZ by optimizing the dose of GA and Fe 2+ and pH condition. MTZ removal reached 83% at the GA: Fe 2+ molar ratio of 1:1 (30 μM) and initial pH 5 and 6.2 after 120 min, and the kinetics showed two degradation phases (kobs1 = 0.09636 for the rapid stage and kobs2 = 0.01056 for the slow stage). The Fe 2+ and GA complexes could expand the range of pH applicability and effectively stabilize the regeneration of Fe 2+, which ultimately promoted the decontamination of MTZ. Sulfate radical (SO4 .- ), hydroxyl radicals, and singlet oxygen were proved to exist in this ternary system and contribute to MTZ removal, and SO4 .- played the dominant role. Furthermore, the possible pathways and mechanisms for MTZ degradation were proposed, and the simulation result indicated that the toxicity of degradation intermediates of MTZ were declined. The GA assisted Fe 2+ /PDS system provided an improved promising advanced oxidation process for organic wastewater disposal. Graphical abstract: Image 1 Highlights: Gallic acid (GA) significantly promoted peroxydisulfate (PDS)/Fe 2+ efficiency. GA improved Fe 3+ /Fe 2+ cycle and reactive species generation in PDS/Fe 2+ /GA. Complexation of GA was verified to be primary mechanism in PDS/Fe 2+ /GA. GA enhanced reaction stoichiometric efficiency of PDS/Fe 2+ from 0.58% to 3.57%.