Fabricating of Fe3O4@Ag-MOF nanocomposite and evaluating its adsorption activity for removal of doxorubicin. Issue 13 (6th December 2022)

• Record Type: Journal Article
• Authors: M. El-Metwaly, N.; A. Katouah, H.; El-Desouky, M. G.; El-Bindary, A. A.; El-Bindary, M. A.
• Is Part Of: Journal of environmental science and health. Volume 57:Issue 13/14(2022)
• Page Start: 1099
• Page End: 1115
• Publication Date: 2022-12-06
• Subjects: Adsorption -- magnetic composite -- doxorubicin hydrochloride -- isotherm -- kinetics; Environmental engineering -- Periodicals; Environmental sciences -- Periodicals; Ecology -- periodicals; Hazardous Substances -- periodicals; 628
• DOI: 10.1080/10934529.2022.2156230
• Languages: English
• ISSNs: 1093-4529

Abstract

Abstract: The purpose of this research was to investigate the doxorubicin (DOX) adsorption behavior on Fe3O4@Ag-Metal Organic Framework (Fe3 O4 @Ag-MOF). This adsorbent was effectively prepared using a simple synthetic process. Many instruments, including FTIR, XRD, SEM, TEM, and XPS, were used to characterized the new Fe3 O4 @Ag-MOF. Additionally, the presented Fe3 O4 @Ag-surface MOF's area was shown to be 586.06 m2/g with a size of around 43 nm. The composite that was made has magnetic properties that were quite strong (63.3 emu/g). The produced Fe3 O4 @Ag-MOF was discovered to have a fantastic ability to adsorb the anti-cancer drug DOX, with a 1.72 mmol/g (934.85 mg/g) adsorption capacity. On the basis of changes in temperature, pH, and DOX concentration, the DOX adsorption behavior mechanism was investigated. The adsorption capacity of Fe3 O4 @Ag-MOF for DOX was greater at pH 7.0, according to experimental data. The adsorption equilibrium also demonstrated that the Langmuir adsorption was regulated the best fit to the extracted data compared with the other models. Additionally, the activation energy of adsorption for DOX onto Fe3 O4 @Ag-MOF was determined, indicating the chemisorption process. The adsorption kinetics was shown in the well-known kinetic model of the pseudo-second-order. The adsorption thermodynamic measurements were documented according to according to the enthalpy (ΔH°), entropy(ΔS°), and Gibbs free energy (ΔG°) parameters demonstrated that the reaction was endothermic and spontaneous thermodynamic. The adsorption of DOX onto Fe3 O4 @Ag-MOF from real water samples (tap water, effluent wastewater, and influence wastewater) were investigated. It's interesting that the synthetic adsorbent had great recyclability 72.6 percent in the fifth cycle indicating that it was highly recyclable. After adsorption, the typical Fe3 O4 @Ag-MOF XRD peak intensities and locations were mostly unchanged throughout adsorption indicates the crystalline phase remained steady. The results indicated that Fe3 O4 @Ag-MOF were a good candidate for adsorbing the DOX and treating wastewater.