Direct Photoexcitation of Borate Enabling Minisci Reaction. Issue 1 (5th November 2021)

• Record Type: Journal Article
• Authors: Kemmochi, Marin; Miyamoto, Yusuke; Sumida, Yuto; Ohmiya, Hirohisa
• Is Part Of: Asian journal of organic chemistry. Volume 11:Issue 1(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-11-05
• Subjects: Alkyl radical -- Borate complex -- Direct photoexcitation -- Minisci reaction; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.202100640
• Languages: English
• ISSNs: 2193-5807

Abstract

Abstract: The photoexcitable borate enabling Minisci C−H alkylation of heteroarene has been described. This protocol using alkylborate only needed O2 and visible light, which provides a considerably clean system. The direct photoexcitation of alkylborate allowed the generation of tertiary, secondary, and primary ‐alkyl radical including methyl radical. This light‐driven Minisci reaction gave a choice for the functionalization of heteroarenes. Abstract : The photoexcitable borate enabling Minisci alkylation of heteroarene has been described. This protocol using alkylborate only needed O2 and visible light, which provides a considerably clean system. The direct photoexcitation of alkylborate allowed the generation of tertiary, secondary, and primary ‐alkyl radical including methyl radical.