A {Ni12}‐Wheel‐Based Metal–Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide. Issue 6 (10th January 2022)

• Record Type: Journal Article
• Authors: Han, Zongsu; Li, Jiangnan; Lu, Wanpeng; Wang, Kunyu; Chen, Yinlin; Zhang, Xiaoping; Lin, Longfei; Han, Xue; Teat, Simon J.; Frogley, Mark D.; Yang, Sihai; Shi, Wei; Cheng, Peng
• Is Part Of: Angewandte Chemie international edition. Volume 61:Issue 6(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-01-10
• Subjects: binding sites -- in situ synchrotron single-crystal X-ray diffraction -- metal–organic frameworks -- SO2 and NO2 adsorption; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202115585
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Air pollution by SO2 and NO2 has caused significant risks on the environment and human health. Understanding the mechanism of active sites within capture materials is of fundamental importance to the development of new clean‐up technologies. Here we report the crystallographic observation of reversible coordinative binding of SO2 and NO2 on open Ni II sites in a metal‐organic framework (NKU‐100) incorporating unprecedented {Ni12 }‐wheels; each wheel exhibits six open Ni II sites on desolvation. Immobilised gas molecules are further stabilised by cooperative host‐guest interactions comprised of hydrogen bonds, π⋅⋅⋅π interactions and dipole interactions. At 298 K and 1.0 bar, NKU‐100 shows adsorption uptakes of 6.21 and 5.80 mmol g −1 for SO2 and NO2, respectively. Dynamic breakthrough experiments have confirmed the selective retention of SO2 and NO2 at low concentrations under dry conditions. This work will inspire the future design of efficient sorbents for the capture of SO2 and NO2 . Abstract : The crystallographic observation of reversible coordinative binding of SO2 and NO2 on open Ni II sites in a robust metal–organic framework (NKU‐100) incorporating unprecedented {Ni12 }‐wheels has been achieved by in situ synchrotron single crystal X‐ray diffraction.