A Highly Selective Supramolecule Array Membrane Made of Zero‐Dimensional Molecules for Gas Separation. Issue 38 (13th August 2021)

• Record Type: Journal Article
• Authors: Zhao, Meng; Ban, Yujie; Yang, Kun; Zhou, Yingwu; Cao, Na; Wang, Yuecheng; Yang, Weishen
• Is Part Of: Angewandte Chemie international edition. Volume 60:Issue 38(2021)
• Page Start: 20977
• Page End: 20983
• Publication Date: 2021-08-13
• Subjects: precombustion carbon capture -- separation -- supramolecule array membrane -- zero-dimensional building blocks; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202108185
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: We orderly assembled zero‐dimensional 2‐methylimidazole (mim) molecules into unprecedented supramolecule array membranes (SAMs) through solvent‐free vapor processing, realizing the intermolecular spacing of mim at ca. 0.30 nm available as size‐sieving channels for distinguishing the tiny difference between H2 (kinetic diameter: 0.289 nm) and CO2 (kinetic diameter: 0.33 nm). The highly oriented and dense membranes yield a separation factor above 3600 for equimolar H2 /CO2 mixtures, which is one order of magnitude higher than those of the state‐of‐the‐art membranes defining 2017's upper bound for H2 /CO2 separation. These SAMs define a new benchmark for molecular sieve membranes and are of paramount importance to precombustion carbon capture. Given the range of supramolecules, we anticipate SAMs with variable intermolecular channels could be applied in diversified separations that are prevalent in chemical processes. Abstract : 2‐Methylimidazole (mim) molecules were assembled into unprecedented supramolecule array membranes (SAMs) through vapor processing on closely packed MOF layers. Selective gas transport through the intermolecular spacing of mim (ca. 0.30 nm) is realized within SAMs, yielding an extremely precise sieving of H2 from CO2 .