Visible‐Light‐Driven One‐Pot Synthesis of Benzimidazoles, Benzothiazoles, and Quinazolinones Catalyzed by Scalable and Reusable Ba‐Doped CoMoO4 Nanoparticles Under Air Atmosphere. Issue 4 (30th December 2022)

• Record Type: Journal Article
• Authors: Abinaya, Ramanjulu; Elavarasan, Selvaraj; Binish, B.; Mani Rahulan, K.; Balasubramanian, Kalpattu K.; Manokaran, Kamaraj; Varathan, Elumalai; Baskar, Baburaj
• Is Part Of: European journal of organic chemistry. Volume 26:Issue 4(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-12-30
• Subjects: benzimidazole -- benzothiazole -- heterogeneous catalysis -- photo-redox catalysis; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.202201098
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: Herein we report a simple and efficient oxidative coupling of various aryl methyl amines with diverse coupling partners, such as o ‐phenylenediamine (benzene‐1, 2‐diamine), 2‐aminobenzenethiol and 2‐aminobenzamide, to synthesize the corresponding heterocycles using scalable and reusable heterogeneous catalysts under visible light irradiation. A systematic investigation led to the synthesis of benzimidazoles, benzothiazoles and quinazolinones under air atmosphere in very good to excellent yields. The strategy is atom economical and found to be tolerance towards different functional groups, and wide range of substrate scope. Furthermore, the methodology was demonstrated for its suitability on scale up and reusability. The density functional theory (DFT) calculations and the analysis of band structures of pristine and Ba doped CoMoO4 systems showed that the doping of Ba in place of Co improved the catalytic performance of the system. Abstract : This work reports the visible light mediated oxidative coupling of aryl methyl amines with o ‐phenylenediamine, 2 ‐aminobenzenethiol and 2 ‐aminobenzamide to benzimidazoles, benzothiazoles, and quinazolinones in one pot using scalable and reusable heterogeneous Ba‐doped CoMoO4 nanoparticles under air atmosphere.