Synthesis of magnetic graphene oxide-titanate composites for efficient removal of Pb(II) from wastewater: Performance and mechanism. (15th February 2020)

• Record Type: Journal Article
• Authors: Yang, Xiutao; Guo, Na; Yu, Yong; Li, Haiyan; Xia, Hui; Yu, Hongwen
• Is Part Of: Journal of environmental management. Volume 256(2020)
• Publication Date: 2020-02-15
• Subjects: Magnetic composite -- Titanate -- Graphene oxide -- Pb(II) -- Adsorption; Environmental policy -- Periodicals; Environmental management -- Periodicals; Environment -- Periodicals; Ecology -- Periodicals; 363.705
• DOI: 10.1016/j.jenvman.2019.109943
• Languages: English
• ISSNs: 0301-4797

Abstract

Abstract: Magnetic graphene oxide-titanate composites (MGO@TNs) were synthesized via growing titanate nanosheets on the graphene oxide sheets with magnetite nanoparticles anchored on. The as-prepared MGO@TNs showed a hierarchical structure and large specific surface area (193.4 m 2 /g), which were suitable for rapid and effective adsorption of Pb(II) from wastewater. Moreover, the loaded magnetite nanoparticles guaranteed the effective magnetic separation of MGO@TNs, avoiding secondary pollution. The adsorption mechanism were illuminated to be ion exchange and surface complexation. Batch adsorption experiments showed the maximum adsorption capacity of MGO@TNs reached 322.7 mg/g for Pb(II) removal. The removal efficiency retained 89.6% after six adsorption-desorption cycles. In addition, the efficiency reached up to 99.8% when applying MGO@TNs for removal of Pb(II) from simulated realistic battery wastewater, ensuring the safe discharge of treated water. The good adsorption performance, recyclability and easy magnetic separation ability made sure that the MGO@TNs has great potential for purification of Pb(II) contaminated wastewater. Graphical abstract: Image 1 Highlights: Magnetic Graphene Oxide-Titanate Composites (MGO@TNs) were synthesized. MGO@TNs can rapidly and effectively eliminate Pb(II) from wastewater. The loaded magnetite nanoparticles guaranteed the effective magnetic separation. Ion exchange and surface complexation were the main adsorption mechanism.