A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions. Issue 44 (15th June 2020)

• Record Type: Journal Article
• Authors: Bai, Pu; Dong, Zhuoya; Wang, Shuang; Wang, Xiangyu; Li, Yue; Wang, Yunzheng; Ma, Yanhang; Yan, Wenfu; Zou, Xiaodong; Yu, Jihong
• Is Part Of: Angewandte Chemie international edition. Volume 59:Issue 44(2020)
• Page Start: 19539
• Page End: 19544
• Publication Date: 2020-06-15
• Subjects: aluminum oxyhydroxide -- anion exchange -- cationic frameworks -- metal oxyanions -- selective capture; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202005878
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Cationic framework materials, especially pure inorganic cationic frameworks that can efficiently and selectively capture harmful heavy metal oxyanions from aqueous solution are highly desired yet scarcely reported. Herein, we report the discovery of a 2D cationic aluminum oxyhydroxide, JU‐111, which sets a new benchmark for heavy metal oxyanion sorbents, especially for Cr VI . Its structure was solved based on 3D electron diffraction tomography data. JU‐111 shows fast sorption kinetics (ca. 20 min), high capture capacity (105.4 mg g −1 ), and broad working pH range (3–10) toward Cr VI oxyanions. Unlike layered double hydroxides (LDHs), which are poorly selective in the presence of CO3 2−, JU‐111 retains excellent selectivity for Cr VI even under a large excess of CO3 2− . These superior features coupled with the ultra‐low cost and environmentally benign nature make JU‐111 a promising candidate for toxic metal oxyanion remediation as well as other potential applications. Abstract : Trapping layers : The first layered cationic aluminum oxyhydroxide, JU‐111, was synthesized, and its structure was determined from 3D electron diffraction tomography data. JU‐111 is a promising candidate for trapping Cr VI from aqueous solutions through anion exchange, showing high sorption capacity, ultrafast kinetics, broad working pH range, and excellent selectivity.