Carbon Dioxide Electroreduction: Efficient Electron Transfer from Electron‐Sponge Polyoxometalate to Single‐Metal Site Metal–Organic Frameworks for Highly Selective Electroreduction of Carbon Dioxide (Small 20/2021). Issue 20 (20th May 2021)

• Record Type: Journal Article
• Authors: Sun, Ming‐Liang; Wang, Yi‐Rong; He, Wen‐Wen; Zhong, Rong‐Lin; Liu, Qing‐Zhi; Xu, Shiyou; Xu, Jing‐Mei; Han, Xiao‐Long; Ge, Xueying; Li, Shun‐Li; Lan, Ya‐Qian; Al‐Enizi, Abdullah M.; Nafady, Ayman; Ma, Shengqian
• Is Part Of: Small. Volume 17:Issue 20(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-05-20
• Subjects: carbon dioxide reduction reaction -- directional electron transfer -- electrocatalysis -- metal–organic frameworks -- polyoxometalates; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202170095
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract : By combining the superiority of polyoxometalate (POM) and single‐metal site Co in porphyrin, a POM‐based metal–organic framework composite has been constructed by Wen‐Wen He, Ya‐Qian Lan, Shengqian Ma, and co‐workers (article number 2100762 ). Directional electron transfer from POM to the single‐metal site Co in PCN‐222(Co) accelerates electron‐transfer efficiency thereby affording high electrocatalytic CO2 reduction reaction activity.