Ultrafast black-color tunability of electrochromic dimming films using cobalt polyoxometalate-anchored nickel oxide nanoparticles. Issue 6 (25th January 2023)

• Record Type: Journal Article
• Authors: Jang, Hwandong; Kim, Jinbo; Han, Minsu; Cho, Cheolhyun; Kim, Eunkyoung
• Is Part Of: Journal of materials chemistry. Volume 11:Issue 6(2023)
• Page Start: 3038
• Page End: 3050
• Publication Date: 2023-01-25
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d2ta07757d
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A black color tunability of an electrochromic (EC) dimming device was explored using cobalt polyoxometalate (CoPW)-anchored nickel oxide nanoparticles (CoPW@NiOx). Abstract : A black color tunability of an electrochromic (EC) dimming device was explored using cobalt polyoxometalate (CoPW)-anchored nickel oxide nanoparticles (CoPW@NiOx). The CoPW@NiOx layer enhanced not only the anodic EC properties of NiOx but also the cathodically coloring EC polymer (poly(3, 3-bis(bromomethyl)-3, 4-dihydro-2 H -thieno[3, 4- b ][1, 4]dioxepine)) arising from the charge balancing effect boosted by CoPW. In particular, PCN400 with a 400 nm-thick CoPW@NiOx layer, achieved black EC switching with high transparency modulation from 73% to 3%, a response time of 0.4 s, and long endurance of over 3000 cycles at a low operating voltage between 1.5 and −1.5 V. PCN400 blocked light transmission up to 95%, and dimming was adaptable to voltage steps, even under an intense light exposure of 2379 cd cm −2 . These adaptable EC devices afforded visual comfort for a display and convertible functionality between the AR and VR. Thus, PCN400 could be coupled with various devices, including smart windows, transparent displays, image sensors, and augmented reality systems.