Mechanistic Study of the Aqueous Reaction of Organic Peroxides with HSO3− on the Surface of a Water Droplet. (11th August 2021)

• Record Type: Journal Article
• Authors: Li, Hao; Wang, Xiao; Zhong, Jie; Chu, Biwu; Ma, Qingxin; Zeng, Xiao Cheng; Francisco, Joseph S.; He, Hong
• Is Part Of: Angewandte Chemie. Volume 133:Number 37(2021)
• Page Start: 20362
• Page End: 20365
• Publication Date: 2021-08-11
• Subjects: aqueous surface -- HSO3− -- organic peroxides -- sulfates; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202105416
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Aqueous reactions between organic peroxides and SO2 are of intense interest in atmospheric science because of their ubiquitous implications for sulfate formation in secondary aerosols. However, the relative yields of the reaction products (inorganic vs. organic sulfates) remain controversial (i.e., 90 % vs. 40–70 % for inorganic sulfate) due in part to the lack of understanding of the underlying reaction mechanisms. Here, our computational results suggest that the reactions of HSO3 − (dissolved SO2 ) with organic peroxides are initiated on the surface of water nanodroplets and then proceed under two reaction pathways, in which the S atom of HSO3 − attacks either the O1 or O2 atom of the peroxide group ‐O(O2)O(O1)H, leading to the formation of inorganic and organic sulfates, respectively. Notably, we find that thse reaction initiated by O1 atom exhibits a relatively low energy barrier and high reaction rate, which favours the formation of inorganic sulfate. Abstract : The organic peroxide–HSO3 − reaction at the aqueous surface proceeds through two pathways, leading to the formation of inorganic and organic sulfates, respectively. The results have important atmospheric implications.