Cobalt Catalyst‐Controlled Selective Dioxygenation of Styrenes Using N‐Hydroxyphthalimide with Molecular Oxygen. Issue 1 (11th October 2021)

• Record Type: Journal Article
• Authors: Hao, Xiaosong; Ji, Huihui; Zhan, Hongju; Zhang, Qian; Li, Dong
• Is Part Of: Advanced synthesis & catalysis. Volume 364:Issue 1(2022)
• Page Start: 193
• Page End: 199
• Publication Date: 2021-10-11
• Subjects: Cobalt -- Dioxygenation -- Styrene -- N-Hydroxyphthalimide -- Oxygen; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.202100921
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: A cobalt‐catalyzed selective dioxygenation of styrenes with N ‐hydroxyphthalimide (NHPI) was developed using molecular oxygen as the terminal oxidant. Alcohol and ketone products can be selectively formed from identical substrates by catalyst control. The reaction was applicable to a broad range of styrenes and exhibited good functional group tolerance. It provided a method for preparation of 1, 2‐diol or α‐hydroxyketone derivatives. Abstract :