Scalable Al2O3–TiO2 Conductive Oxide Interfaces as Defect Reservoirs for Resistive Switching Devices. (14th November 2022)

• Record Type: Journal Article
• Authors: Li, Yang; Wang, Wei; Zhang, Di; Baskin, Maria; Chen, Aiping; Kvatinsky, Shahar; Yalon, Eilam; Kornblum, Lior
• Is Part Of: Advanced Electronic Materials. Volume 9:Number 2(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-11-14
• Subjects: atomic layer deposition -- conductive oxide interfaces -- resistive switching -- resistive switching memory -- 2D electron gas -- valence change memory; Materials -- Electric properties -- Periodicals; Materials science -- Periodicals; Magnetic materials -- Periodicals; Electronic apparatus and appliances -- Periodicals; 537
• DOI: 10.1002/aelm.202200800
• Languages: English
• ISSNs: 2199-160X

Abstract

Abstract: Resistive switching devices herald a transformative technology for memory and computation, offering considerable advantages in performance and energy efficiency. Here, a simple and scalable material system of conductive oxide interfaces is employed, and their unique properties are leveraged for a new type of resistive switching device. An Al2 O3 –TiO2 ‐based valence‐change resistive switching device, where the conductive oxide interface serves both as the bottom electrode and as a reservoir of defects for switching, is demonstrated. The amorphous–polycrystalline Al2 O3 –TiO2 conductive interface is obtained following the technological path of simplifying the fabrication of the 2D electron gases (2DEGs), making them scalable for practical mass integration. Physical analysis of the device chemistry and microstructure with comprehensive electrical analysis of its switching behavior and performance is combined. The origin of the resistive switching is pinpointed to the conductive oxide interface, which serves both as the bottom electrode and as a reservoir of oxygen vacancies. The latter plays a key role in valence‐change resistive switching devices. The new device, based on scalable and complementary metal–oxide–semiconductor (CMOS)‐technology‐compatible fabrication processes, opens new design spaces toward increased tunability and simplification of the device selection challenge. Abstract : Conductive oxide interfaces are gaining considerable traction for oxide electronics. In this work, such interfaces are formed using the highly scalable atomic layer deposition technique. These are then crafted into resistive switching devices, where the interface functions both as the back electrode and the source of defects for switching. This demonstration paves the way toward new types of self‐rectifying devices.