Precise Molecular Design for Two Parent BN‐Pentacyclic Isomers Through Stitching Engineering Toward Extremely Sensitive Explosive Detection (Advanced Optical Materials 3/2023). Issue 3 (3rd February 2023)

• Record Type: Journal Article
• Authors: Huang, Huanan; Yao, Junxiong; Xu, Han; Li, Jiaqi; Wang, Hanbin; Xiong, Cheng; Fang, Binhua; Wang, Yawei; Zhou, Ying; Cao, Xiaohua; Wang, Jianguo; Tang, Ben Zhong
• Is Part Of: Advanced optical materials. Volume 11:Issue 3(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-02-03
• Subjects: BN/CC isosterism -- boron‐nitrogen aromatics -- mechanisms for explosive detection -- stitching engineering -- TNP detection; Optical materials -- Periodicals; Photonics -- Periodicals; 620.11295
• DOI: 10.1002/adom.202370007
• Languages: English
• ISSNs: 2195-1071

Abstract

Abstract : The boron‐nitrogen (BN) aromatic compounds represent a unique hybrid system and display attractive photophysical and chemical properties. In article number 2202433, Huanan Huang, Jianguo Wang, Ben Zhong Tang, and co‐workers design two BN‐pentacyclic isomers through stitching engineering. Systematic research revealed that the crystal structure, aromaticity and photophysical properties vary with the change of BN embedded patterns, indicating that precise control of stitching pattern is of great importance to effectively modulate molecular properties. Such a discovery vastly extends knowledge of the structure and functionality of BN‐doped polycyclic aromatic hydrocarbons, making them very encouraging in the materials chemistry field.