Visible‐light Induced Cerium‐catalyzed N‐Demethylation of N‐Methyl Amides under Air Conditions. Issue 3 (24th January 2023)

• Record Type: Journal Article
• Authors: Teng, Qing‐Hu; Sun, Gui‐Xia; Huang, Fang‐Ping; Wang, Kai; Liang, Fu‐Pei
• Is Part Of: Advanced synthesis & catalysis. Volume 365:Issue 3(2023)
• Page Start: 307
• Page End: 311
• Publication Date: 2023-01-24
• Subjects: Visible-light induced -- Cerium-catalyzed -- N-demethylation -- N-methyl amides; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.202201176
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: A visible‐light induced cerium‐catalyzed N ‐demethylation of N ‐methyl amides under air atmosphere to the corresponding of N ‐demethylated amides is presented. Upon irradiation the excited states of [Ce IV Cln ] 2− are able to activate N ‐methyl amides. This reaction provides a methodology to cleave the C−N bond of amides under air conditions. Abstract :