Improving Electrochemical Activity of P2‐type Na2/3Mn2/3Ni1/3O2 by Controlling its Crystallinity. Issue 2 (13th December 2022)

• Record Type: Journal Article
• Authors: Kataoka, Riki; Taguchi, Noboru; Tada, Kohei; Machida, Akihiko; Takeichi, Nobuhiko
• Is Part Of: Batteries & supercaps. Volume 6:Issue 2(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-12-13
• Subjects: crystallinity -- electrochemical activity -- P2-type layered oxide material -- sodium-ion battery -- transitions metal; Electrochemistry -- Periodicals; Electrodes -- Periodicals; Electric batteries -- Periodicals; 621.31242
• DOI: 10.1002/batt.202200462
• Languages: English
• ISSNs: 2566-6223

Abstract

Abstract: Layered P2‐type Na containing manganese‐nickel oxide (Na2/3 (Mn2/3 Ni1/3 )O2 ) materials show relatively higher electrochemical capacity. The electrochemical performance of Na2/3 (Mn2/3 Ni1/3 )O2 decreases during cycling when more than 1/2 of Na was extracted owing to the structural change with large volume change and oxygen emission. We found that smaller crystallite size and introduction of the defects at transition metal site of Na2/3 (Mn2/3 Ni1/3 )O2 plays a key role to improve its cycling performance. The structural analysis observations using X‐ray total scattering analysis, X‐ray absorption fine structure (XAFS) and transmission electron microscopy (TEM), revealed that the length and numbers of stacks of the MO2 layers were shortened and decreased, respectively, compared to that of P2‐type layered Na2/3 (Mn2/3 Ni1/3 )O2 . This short‐range ordering of the layered structure restricts the structural change during cycling resulting in mitigating large volume changes. Moreover, the metal defects at the transition metal site of the Na2/3 (Mn2/3 Ni1/3 )O2 increases the contribution of the oxygen redox which confirmed by the density functional theory calculation, without showing significant overpotential and capacity fading during cycling. Abstract : Changing crystallinity : Generally, lowering the crystallinity of the layered oxide materials lowers their electrochemical performance. However, we found that the cycling performance of Na2/3 Mn2/3 Ni1/3 O2 with P2‐type layered oxide significantly improved by lowering its crystallinity without a significant decrease in the reversible capacity and average potential by the ball milling.