High-useful yield and new autoionizing state of resonantly ionized tungsten. Issue 2 (10th January 2023)

• Record Type: Journal Article
• Authors: Shulaker, Danielle Ziva; Trappitsch, Reto; Savina, Michael R.; Isselhardt, Brett
• Is Part Of: Journal of analytical atomic spectrometry. Volume 38:Issue 2(2023)
• Page Start: 457
• Page End: 463
• Publication Date: 2023-01-10
• Subjects: Atomic spectra -- Periodicals; Atomic absorption spectroscopy -- Periodicals; 543.0858
• DOI: 10.1039/d2ja00320a
• Languages: English
• ISSNs: 0267-9477

Abstract

Abstract : This work presents a new RIS scheme for W with ∼15% useful yield using three tunable Ti:Sa lasers as determined by conducting spectroscopic surveys and saturation experiments. Abstract : In order to measure tungsten isotopic composition in presolar stardust grains that contain a limited number of atoms, we developed a new three-photon three-color resonance ionization scheme using titanium:sapphire lasers and the Laser Ionization of Neutrals (LION) instrument at Lawrence Livermore National Laboratory. The first two transitions can be easily saturated, while approximately 84% of available atoms can be ionized in the third transition with our current laser irradiance. When ionizing from the ground state, measurements demonstrate a W useful yield of 14.4% ± 1.6%. Experiments that intentionally cover a range of laser power and wavelength to simulate potential variations during analysis show that laser-induced W isotopic fractionation, if it occurs, is within measurement error. Overall, this new W resonance ionization scheme can be employed in future studies of atom limited samples to obtain W isotopic measurements.