A multicomponent equimolar proton-conducting quadruple hexagonal perovskite-related oxide system. Issue 7 (31st January 2023)

• Record Type: Journal Article
• Authors: Ullah, Abid; Hussain, Basharat; Youn, Yong; Bae, Hyung-Bin; Hong, Jong-Eun; Joh, Dong Woo; Lee, Seung-Bok; Song, Rak-Hyun; Kim, Tae Woo; Lim, Tak-Hyoung; Kim, Hye-Sung
• Is Part Of: Dalton transactions. Volume 52:Issue 7(2023)
• Page Start: 1885
• Page End: 1894
• Publication Date: 2023-01-31
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt02897b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Since the high configurational entropy-driven structural stability of a multicomponent oxide system was proposed by Rost et al. in 2015, many experiments and simulations have been done to develop new multicomponent oxides. Abstract : Since the high configurational entropy-driven structural stability of multicomponent oxide system was proposed Rost et al. in 2015, many experiments and simulations have been done to develop new multicomponent oxides. Although many notable findings have shown unique physical and chemical properties, high configurational entropy oxide systems that have more than 3 distinct cation sites are yet to be developed. By utilizing atomic-scale direct imaging with scanning transmission electron microscopy and AC-impedance spectroscopy analysis, we demonstrated for the first time that a multicomponent equimolar proton-conducting quadruple hexagonal perovskite-related Ba5 RE2 Al2 ZrO13 (RE = rare earth elements) oxide system can be synthesized even when adding eight different rare earth elements. In particular, as the number of added elements was increased, i.e., as the configurational entropy was increased, we confirmed that the chemical stability toward CO2 was improved without a significant decrement of the proton conductivity. The findings in this work broaden the use of the crystal structure to which the multicomponent model can be applied, and a systematic study on the correlation between the configurational entropy and proton conductivity and/or chemical stability is noteworthy.