Hydrosilylation of Alkynes Under Continuous Flow Using Polyurethane‐Based Monolithic Supports with Tailored Mesoporosity. Issue 1 (7th August 2022)

• Record Type: Journal Article
• Authors: Acikalin, Hande; Panyam, Pradeep K. R.; Shaikh, Abdul Wasif; Wang, Dongren; Kousik, Shravan R.; Atanasova, Petia; Buchmeiser, Michael R.
• Other Names: Lederer Albena guestEditor.; Mutlu Hatice guestEditor.
• Is Part Of: Macromolecular chemistry and physics. Volume 224:Issue 1(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-08-07
• Subjects: hydrosilylation -- mesoporous -- monolith -- polyurethane -- rhodium; Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.202200234
• Languages: English
• ISSNs: 1022-1352

Abstract

Abstract: Non‐porous polyurethane‐based monoliths are prepared under solvent‐induced phase separation conditions. They possess low specific surface areas of 0.15 m 2 g −1, pore volumes of 1 µL g −1, and a non‐permanent, solvent‐induced microporosity with pore dimensions ≤1 nm. Mesoporosity can be introduced by varying the monomers and solvents. A tuning of the average solubility parameter of the solvent mixture by increasing the macroporogen content results in a decrease in the volume fraction of micropores from 70% to 40% and an increase in the volume fraction of pores in the range of 1.7–9.6 nm from 22% to 41% with only minor changes in the volume fraction of larger mesopores in the range of 9.6–50 nm. The polymeric monoliths are functionalized with quaternary ammonium groups, which allowed for the immobilization of an ionic liquid that contained the ionic Rh‐catalyst [1‐(pyrid‐2‐yl)‐3‐mesityl)‐imidazol‐2‐ylidene))( η 4 ‐1, 5‐cyclooctadiene)Rh(I) tetrafluoroborate]. The supported catalyst is used in the hydrosilylation of 1‐alkynes with dimethylphenylsilane under continuous flow using methyl‐ tert ‐butyl ether as second liquid transport phase. E/Z ‐selectivity in hydrosilylation is compared to the one of the analogous biphasic reactions. The strong increase in Z ‐selectivity is attributed to a confinement effect provided by the small mesopores. Abstract : The synthesis of non‐porous polyurethane‐based monoliths and the tailoring of mesoporosity via a solvent‐induced phase separation process resulting in the first mesoporous polyurethane‐based monoliths with tailored mesopores in the 2–10 nm range is reported. Monoliths are surface‐functionalized and used as catalyst supports in the Rh‐catalyzed hydrosilylation of 1‐alkynes.