Removal of ceftriaxone sodium antibiotic from pharmaceutical wastewater using an activated carbon based TiO2 composite: Adsorption and photocatalytic degradation evaluation. (March 2023)

• Record Type: Journal Article
• Authors: Abdullah, Muneeb; Iqbal, Javed; Ur Rehman, Muhammad Saif; Khalid, Usman; Mateen, Fahad; Arshad, Salman Noshear; Al-Sehemi, Abdullah G.; Algarni, Hamed; Al-Hartomy, Omar A.; Fazal, Tahir
• Is Part Of: Chemosphere. Volume 317(2023)
• Publication Date: 2023-03
• Subjects: Pharmaceutical wastewater -- Antibiotics -- Ceftriaxone sodium -- Corncob activated carbon -- TiO2 photocatalyst; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2023.137834
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: The water pollution becomes a serious concern for the sustainability of ecosystems due to the existence of pharmaceutical products (ceftriaxone (CEF) antibiotic). Even in low concentration of CEF has lethal effects on ecosystem and human health. To remove CEF, TiO2 is considered as an effective and efficient nanoparticles, however its performance is reduced due to wider energy gap and rapid recombination of charge carriers. In this study, activated carbon based TiO2 (ACT-X) heterogeneous nanocomposites were synthesized to improve the intrinsic properties of TiO2 and their adsorption-photocatalytic performance for the removal of CEF. The characterization results revealed that ACT-X composites have slower recombination of charge carriers, lower energy band gap (3.05 eV), and better light absorption under visible region of light. From ACT-X composites, the ACT-4 photocatalyst has achieved highest photocatalytic degradation (99.6%) and COD removal up (99.2%). The results of radical scavengers showed that photocatalytic degradation of CEF is mainly occurred due to superoxide and hydroxyl radicals. Meanwhile, the reusability of ACT-4 up to five cycles shows more than 80% photocatalytic degradation, which make the process more economical. The highest experimental adsorption capacity is achieved up to 844.8 mg g −1 using ACT-4. The favorable and multilayer heterogeneous adsorption is carried out according to the well-fitted data with pseudo-second-order and Freundlich models, respectively. These results indicate that the carbon-based TiO2 composites can be used as a green, stable, efficient, effective, reusable, renewable, and sustainable photocatalyst to eliminate the pharmaceutical pollutants (antibiotics) via adsorption and photocatalytic degradation processes. Graphical abstract: Image 1 Highlights: Activated carbon derived from corncob was successfully coupled with TiO2 for the formation ACT-X composites. ACT-4 shows slower recombination of e − /h +, smaller band gap (3.05 eV), and improved visible light absorbance. ACT-4 achieves more adsorption capacity (844 mg g −1 ) and photocatalytic degradation (99.6%) for CEF. Superoxide and hydroxyl radicals are dominant species to degrade CEF. ACT-4 is more stable, efficient, economical, and reusable for the elimination of CEF.