Binder-free cupric-ion containing zinc sulfide nanoplates-like structure for flexible energy storage devices. (February 2023)

• Record Type: Journal Article
• Authors: Hussain, Iftikhar; Shaheen, Irum; Ahmad, Rabia; Ali, Ijaz; Hussain, Khurshid; Hussain, Sayed Sajid; Alsaiari, Norah Salem; Katubi, Khadijah Mohammedsaleh; Eldin, Sayed M.; Ansari, Mohd Zahid
• Is Part Of: Chemosphere. Volume 314(2023)
• Publication Date: 2023-02
• Subjects: Cu-containing ZnS nanoplates -- Capacity -- Electrode -- Nanomaterials; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2022.137660
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Researchers have been enthusiastic about developing high-performance electrode materials based on metal chalcogenides for energy storage applications. Herein, we developed cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates by using a solvothermal approach. The as-synthesized ZnS:Cu nanoplates electrode was characterized and analyzed by using XRD, SEM, TEM, EDS, and XPS. The binder-free flexible ZnS:Cu nanoplates exhibited excellent specific capacitance of 545 F g −1 at a current density of 1 A g −1 . The CV and GCD measurements revealed that the specific capacitance was mainly attributed to the Faradaic redox mechanism. Further, the binder-free flexible ZnS:Cu nanoplates electrode retained 87.4% along with excellent Coulombic efficiency (99%) after 5000 cycles. The binder-free flexible ZnS:Cu nanoplates exhibited excellent conductivity, specific capacitance, and stability which are beneficial in energy storage systems. These findings will also open new horizons amongst material scientists toward the new direction of electrode development. Graphical abstract: Image 1 Highlights: Cupric ion-containing zinc sulfide (ZnS:Cu) nanoplates was reported. The ZnS:Cu nanoplate electrode exhibited capacity of 218 C g −1 . The ZnS: Cu electrode retained 87.4% cyclic stability after 5000 cycles. The composite exhibited 99% Coulombic efficiency.