Catalyst design for mitigating nitrosamines in CO2 capture process. (August 2015)

• Record Type: Journal Article
• Authors: Chandan, Payal; Honchul, Sarah; Thompson, Jesse; Liu, Kunlei
• Is Part Of: International journal of greenhouse gas control. Volume 39(2015:Aug.)
• Page Start: 158
• Page End: 165
• Publication Date: 2015-08
• Subjects: CO2 capture -- Hydrogenation -- Nickel catalyst -- Nitrosamines -- Solvent recovery approach; Greenhouse gases -- Environmental aspects -- Periodicals; Air -- Purification -- Technological innovations -- Periodicals; Gaz à effet de serre -- Périodiques; Gaz à effet de serre -- Réduction -- Périodiques; Air -- Purification -- Technological innovations; Greenhouse gases -- Environmental aspects; Periodicals; 363.73874605
• DOI: 10.1016/j.ijggc.2015.05.013
• Languages: English
• ISSNs: 1750-5836

Abstract

Graphical abstract: Highlights: Catalytic nitrosamine destruction for aqueous amine solutions has been demonstrated with amine recovery approach. Destruction of >95% of nitrosamine was obtained in 4 h with nickel catalyst. The catalyst was fully characterized and reused up to 15 cycles. Multiple nitrosamines were destroyed simultaneously under hydrogenation condition. Abstract: Nitrosamines formation during amine based CO2 capture process has recently gained strong attention due to potential health and environmental concerns. In this paper, catalytic nitrosamine destruction in aqueous amine solutions with amine recovery approach is proposed. An up-flow fixed-bed reactor was designed for laboratory experiments in which a nitrosamine solvent stream along with hydrogen was passed into the reactor over a selected catalyst bed. A number of Pd, Fe and Ni metal catalysts were synthesized based on metal-support interaction and were evaluated toward nitrosamine hydrogenation. The Ni based catalyst was found to possess excellent activity (>95%) toward the destruction of 100 mg/L nitrosopyrrolidine in 5 mol/kg MEA solution at 120 psi hydrogen pressure and 120 °C temperature in 4 h. Catalyst reusability study was conducted for 15 cycles showed high catalyst activity and stability lasting more than 60 h. This catalyst was prepared by incipient-wetness technique and was characterized by SEM, TPR, N2 adsorption–desorption and XRD to determine its intrinsic structural properties. The catalyst was further studied with several different nitrosamines to prove its utility toward multiple nitrosamines.