Rationalization of passivation strategies toward high-performance perovskite solar cells. (1st December 2022)

• Record Type: Journal Article
• Authors: Zhang, Zhihao; Qiao, Lu; Meng, Ke; Long, Run; Chen, Gang; Gao, Peng
• Is Part Of: Chemical Society reviews. Volume 52:Number 1(2023)
• Page Start: 163
• Page End: 195
• Publication Date: 2022-12-01
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cs00217e
• Languages: English
• ISSNs: 0306-0012

Abstract

Abstract : This review systematically outlines chemical, physical, energetic and field-effect passivation for perovskite solar cells with their corresponding advanced characterization techniques. Abstract : Lead halide perovskite solar cells (PSCs) have shown unprecedented development in efficiency and progressed relentlessly in improving stability. All the achievements have been accompanied by diverse passivation strategies to circumvent the pervasive defects in perovskite materials, which play crucial roles in the process of charge recombination, ion migration, and component degradation. Among the tremendous efforts made to solve these issues and achieve high-performance PSCs, we classify and review both well-established and burgeoning passivation strategies to provide further guidance for the passivation protocols in PSCs, including chemical passivation to eliminate defects by the formation of chemical bonds, physical passivation to eliminate defects by strain relaxation or physical treatments, energetic passivation to improve the stability toward light and oxygen, and field-effect passivation to regulate the interfacial carrier behavior. The subtle but non-trivial consequences from various passivation strategies need advanced characterization techniques combining synchrotron-based X-ray analysis, capacitance-based measurements, spatially resolved imaging, fluorescent molecular probe, Kelvin probe force microscope, etc., to scrutinize the mechanisms. In the end, challenges and prospective research directions on advancing these passivation strategies are proposed. Judicious combinations among chemical, physical, energetic, and field-effect passivation deserve more attention for future high-efficiency and stable perovskite photovoltaics.