Experimental study of the hydrothermal reactivity of oxalic acid under high pressure. Issue 1 (November 2020)

• Record Type: Journal Article
• Authors: Chen, Kefei; Li, Yuanju; Zhang, Chen; Zhou, Shixin; Li, Jing; Li, Pengpeng; Sun, Zexiang; Meng, Bingkun; Fu, Deliang
• Is Part Of: IOP conference series. Volume 600:Issue 1(2020)
• Publication Date: 2020-11
• Subjects: Earth sciences -- Periodicals; Environmental sciences -- Congresses; Environmental sciences -- Periodicals; 550.5
• DOI: 10.1088/1755-1315/600/1/012003
• Languages: English
• ISSNs: 1755-1307

Abstract

Abstract: The thermal stability of organic acids has a close relationship with the formation mechanism of secondary pores in deep reservoirs. Experiments were conducted to investigate the thermal stability of oxalic acid under high pressure and the influence of K-feldspar on oxalic acid decomposition. The experiment temperatures were set in the range of 130-330°C and each experiment was performed for 72h under 60MPa. Results show that both temperature and K-feldspar have significant influence on the decomposition of oxalic acid. The oxalic acid decomposed slowly at temperatures less than 180°C, and most of the oxalic acid decomposed at temperatures between 180°C and 230°C. Besides, the decarboxylation reaction proceeded more slowly in the presence of K-feldspar than the mineral-free experiments, which is most likely attributed to the increasing pH caused by dissolution. In addition, because the decomposition rate of oxalic acid was low, the K-feldspar dissolution was not affected at temperatures lower than 230°C.