Coordination Polymers Containing a Glycine-Derived Trimellitic Acid Imide. Issue 1 (May 2020)

• Record Type: Journal Article
• Authors: Beards, Michael J.; Turner, David R.
• Is Part Of: IOP conference series. Volume 833:Issue 1(2020)
• Publication Date: 2020-05
• Subjects: Materials science -- Periodicals; 620.1105
• DOI: 10.1088/1757-899X/833/1/012062
• Languages: English
• ISSNs: 1757-8981

Abstract

Abstract: A trimellitic imide ligand (GlyTMI 2 -), derived from glycine, has been used in the formation of three coordination polymers as a means towards understanding the role of the aromatic core of the ligand in determining structure. The polymeric structures poly -{(N(CH3 )2 H2 )[Zn2 (GlyTMI)2 (OAc)(DMF)0.5 (CH3 OH)0.5 ]·CH3 OH} (1 ), poly -[Cd2 (GlyTMI)2 (DMF)3 ] (2 ), and poly -{[Cd2 (GlyTMI)2 (4, 4'-bipy)2 ]·2H2 O·DMF} (3 ) have different dimensionalities, attributed to the change in size of the metal ion (Zn vs. Cd).