Iron-rich intermetallics in high pressure die cast A383 aluminum alloys. (November 2020)

• Record Type: Journal Article
• Authors: Liu, Tao; Karkkainen, Mikko; Nastac, Laurentiu; Arvikar, Vish; Levin, Ilya; Brewer, Luke N.
• Is Part Of: Intermetallics. Volume 126(2020:Nov.)
• Publication Date: 2020-11
• Subjects: Intermetallic compounds -- Metallography -- Periodicals; Metallic glasses -- Periodicals; Composés intermétalliques -- Métallographie -- Périodiques; 669.94
• DOI: 10.1016/j.intermet.2020.106814
• Languages: English
• ISSNs: 0966-9795

Abstract

Abstract: This work describes the composition and crystal structure of Fe-rich intermetallics that form during the high pressure die casting (HPDC) process of alloy A383. Engine castings were produced using the HPDC process with A383 material with a nominal iron content of 1 wt %. Quantitative energy dispersive X-ray spectroscopy (EDS) was used to measure the chemical composition of Fe-rich intermetallics that formed during the process, and electron backscattered diffraction (EBSD) was used to identify their corresponding crystal structures and space groups. The results revealed that there were two types of Fe-rich intermetallics: sludge particles with a polygonal morphology and α-Fe with a Chinese-script shape. No needle-like β-Fe intermetallics were observed. Sludge and α-Fe had the same crystal structures, indexed as body-center cubic (bcc) with the same space group of Im 3 ¯ (No. 204). Sludge contained more Mn and Cr than α-Fe, whereas there was a larger concentration of Cu in α-Fe than sludge. ThermoCalc software was used to estimate the formation temperature of Fe-rich intermetallics, and the results suggested that α-Fe (Al8 Fe2 Si) with the bcc crystal structure and sludge were the same phase but formed at different temperatures during solidification process. Highlights: The deleterious, iron-rich intermetallics (β-Fe) are not present in high pressure die cast microstructures due to rapid cooling rates. The "sludge" and α-Fe, while microstructurally distinct, are the same phase, only formed at different points during the solidification process. Both sludge and α-Fe have the same bcc structure with an apparent space group of Im 3 ¯ .