A Metal Nanoparticle Thermistor with the Beta Value of 10 000 K. Issue 5 (4th December 2022)

• Record Type: Journal Article
• Authors: Zhao, Xing; Guo, Jiahui; Wang, Jingyu; Yan, Yong
• Is Part Of: Small. Volume 19:Issue 5(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-12-04
• Subjects: flexible -- ionic charges -- metal nanoparticles -- thermistors -- ultrahigh sensitivity; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202205136
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: The thermistor, typically made from metallic oxides, is a type of resistor whose electrical resistance is dependent on its temperature. Despite the wide usage, the limitations of ceramic thermistors become increasingly apparent as devices with improved performances are sought and as new applications emerge. Herein, a thermistor that is showed with a beta (B) value of 10 000 K can be made exclusively from metal nanoparticles functionalized with charged organic ligands. This B value is hard to achieve for ceramic devices, which is due to the increase of effective counterion concentration and its mobility upon thermal activation. Importantly, the performance of the nanoparticle thermistor is maintained when it is fabricated on a flexible substrate and experiences reversible bending. Demos of thermistor arrays for heat transfer, distribution, and comparison of their performance with commercial products are also demonstrated. Owing to the low temperature and simple casting process, conformably flexible characteristics, stable solid states, and ultra‐high sensitivities, this device is expected to be practically used soon. Abstract : A thermistor with state‐of‐the‐art performance is produced exclusively from metal nanoparticles functionalized with charged organic ligands. Importantly, the performance of this thermistor is maintained when it is fabricated on a flexible substrate, and experiences reversible bending. In addition, this thermistor is used to monitor the change in room temperature that shows comparable to the best performed commercial resistance temperature detectors.