Ceramic Wafer Scintillation Screen by Utilizing Near‐Unity Blue‐Emitting Lead‐Free Metal Halide (C8H20N)2Cu2Br4. (18th November 2022)

• Record Type: Journal Article
• Authors: Su, Binbin; Jin, Jiance; Han, Kai; Xia, Zhiguo
• Is Part Of: Advanced functional materials. Volume 33:Number 5(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-11-18
• Subjects: metal halides -- radioluminescence -- scintillators -- X‐ray imaging; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202210735
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Scintillators with high light yield, low detection limit, large X‐ray attenuation efficiency as well as stable and nontoxic compositions are of great importance for radiation detection applications. Here, 0D (C8 H20 N)2 Cu2 Br4 single crystals are obtained and show blue emission peaking at 468 nm with a near‐unity photoluminescence quantum yield of 99.7%, a large Stokes shift of 148 nm (i.e., negligible self‐absorption), and a good environmental stability along with strong X‐ray absorption capability. Moreover, a high light yield of up to ≈ 91 300 photons/MeV and a low detection limit of 52.1 nGyair s −1 are realized, which is more than one hundred times lower than the dose rate of 5.5 µGyair s −1 required for X‐ray medical diagnostics. (C8 H20 N)2 Cu2 Br4 ceramic wafer scintillation screen is fabricated by a cold pressing sintering process, and the clear contrast images of opaque metal box and electronic component with a spatial resolution of 9.54 lp mm −1 are realized. This study not only designs a new lead‐free metal halide scintillator, but also develops a universal strategy for the preparation of large‐sized scintillator screen in nondestructive X‐ray imaging. Abstract : Blue‐emitting (C8 H20 N)2 Cu2 Br4 crystals show a photoluminescence quantum yield (PLQY) of 99.7% and a Stokes shift of 148 nm, originating from d 9 s 1 → d 10 metal‐centered transition. The high PLQY combined with negligible self‐absorption and strong X‐ray absorption capability enable a high light yield of ≈ 91 300 photons/MeV and low detection limit of 52.1 nGyair s −1 and the spatial resolution of 9.54 lp mm −1 in nondestructive X‐ray imaging. The nontoxicity, good stability and outstanding radioluminescence properties make (C8 H20 N)2 Cu2 Br4 scintillator exhibits potential application in medical digital radiography.